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Chapter 13

Molecular Vibrational Spectroscopy

Infrarot (IR)-Spektroskopie: Überblick
Infrarot (IR)-Spektroskopie: Überblick
When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation ...
IR-Spektroskopie: Molekulare Schwingungen im Überblick
IR-Spektroskopie: Molekulare Schwingungen im Überblick
When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental ...
IR-Spektroskopie: Hooke'sche Approximation molekularer Schwingungen nach dem Hookeschen Gesetz
IR-Spektroskopie: Hooke'sche Approximation molekularer Schwingungen nach dem Hookeschen Gesetz
A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond ...
IR-Spektrometer
IR-Spektrometer
There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR ...
IR-Spektrum
IR-Spektrum
When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's ...
IR-Absorptionsfrequenz: Hybridisierung
IR-Absorptionsfrequenz: Hybridisierung
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on ...
IR-Absorptionsfrequenz: Delokalisierung
IR-Absorptionsfrequenz: Delokalisierung
Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or ...
IR-Frequenzbereich: X-H-Dehnung
IR-Frequenzbereich: X-H-Dehnung
In IR spectroscopy, signals produced by the X−H bonds (such as C−H, O−H, or N−H) can be observed in the frequency range of  ...
IR-Frequenzbereich: Alkin- und Nitrildehnung
IR-Frequenzbereich: Alkin- und Nitrildehnung
Both alkyne (C≡C) and nitrile (C≡N) functional groups contain triple bonds and show stretching absorptions around the wavenumber range of 2100 ...
IR-Frequenzbereich: Alken- und Carbonyldehnung
IR-Frequenzbereich: Alken- und Carbonyldehnung
Double bonds in alkenes and carbonyl compounds exhibit stretching frequencies in the diagnostic region of the IR spectrum. In addition, alkenes exhibit ...
IR-Frequenzbereich: Fingerabdruck-Bereich
IR-Frequenzbereich: Fingerabdruck-Bereich
IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 ...
Peakintensität des IR-Spektrums: Anzahl der IR-aktiven Bindungen
Peakintensität des IR-Spektrums: Anzahl der IR-aktiven Bindungen
When infrared radiation is passed through a molecule, absorption occurs if the molecule's vibration leads to a substantial change in its bond dipole ...
Spitzenintensität des IR-Spektrums: Dipolmoment
Spitzenintensität des IR-Spektrums: Dipolmoment
The dipole moment of a bond is the product of the partial charge on either atom and the distance between them. Dipole moments influence the efficiency of ...
Peakverbreiterung des IR-Spektrums: Wasserstoffbrückenbindung
Peakverbreiterung des IR-Spektrums: Wasserstoffbrückenbindung
The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker ...
IR-Spektrum-Peak-Splitting: Symmetrische vs. asymmetrische Schwingungen
IR-Spektrum-Peak-Splitting: Symmetrische vs. asymmetrische Schwingungen
Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these ...
Anwendungen der IR-Spektroskopie: Überblick
Anwendungen der IR-Spektroskopie: Überblick
The non-destructive nature and ability to provide valuable chemical information make IR spectroscopy a versatile technique with broad applications in ...
Abgeschwächte Totalreflexions-Infrarotspektroskopie (ATR): Überblick
Abgeschwächte Totalreflexions-Infrarotspektroskopie (ATR): Überblick
Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely ...
Raman-Spektroskopie: Übersicht
Raman-Spektroskopie: Übersicht
The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of ...
Raman-Spektroskopie-Instrumente: Übersicht
Raman-Spektroskopie-Instrumente: Übersicht
A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector. The monochromatic laser ...
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