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Chapter 13

Molecular Vibrational Spectroscopy

적외선(IR) 분광법: 개요
적외선(IR) 분광법: 개요
When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation ...
IR 분광법: 분자 진동 개요
IR 분광법: 분자 진동 개요
When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental ...
IR 분광법: 분자 진동의 Hooke's Law 근사
IR 분광법: 분자 진동의 Hooke's Law 근사
A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond ...
IR 분광계
IR 분광계
There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR ...
IR 스펙트럼
IR 스펙트럼
When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's ...
IR 흡수 주파수: 혼성화
IR 흡수 주파수: 혼성화
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on ...
IR 흡수 주파수: 비국소화(Delocalization)
IR 흡수 주파수: 비국소화(Delocalization)
Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or ...
IR 주파수 영역: X–H 스트레칭
IR 주파수 영역: X–H 스트레칭
In IR spectroscopy, signals produced by the X−H bonds (such as C−H, O−H, or N−H) can be observed in the frequency range of  ...
IR 주파수 영역: 알킨 및 니트릴 스트레칭
IR 주파수 영역: 알킨 및 니트릴 스트레칭
Both alkyne (C≡C) and nitrile (C≡N) functional groups contain triple bonds and show stretching absorptions around the wavenumber range of 2100 ...
IR 주파수 영역: 알켄 및 카르보닐 스트레칭
IR 주파수 영역: 알켄 및 카르보닐 스트레칭
Double bonds in alkenes and carbonyl compounds exhibit stretching frequencies in the diagnostic region of the IR spectrum. In addition, alkenes exhibit ...
IR 주파수 영역: 지문 영역
IR 주파수 영역: 지문 영역
IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 ...
IR Spectrum Peak Intensity: IR-Active Bonds의 양
IR Spectrum Peak Intensity: IR-Active Bonds의 양
When infrared radiation is passed through a molecule, absorption occurs if the molecule's vibration leads to a substantial change in its bond dipole ...
IR 스펙트럼 피크 강도: 쌍극자 모멘트
IR 스펙트럼 피크 강도: 쌍극자 모멘트
The dipole moment of a bond is the product of the partial charge on either atom and the distance between them. Dipole moments influence the efficiency of ...
IR Spectrum Peak Broadening: 수소 결합
IR Spectrum Peak Broadening: 수소 결합
The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker ...
IR Spectrum Peak Splitting: 대칭 vs 비대칭 진동
IR Spectrum Peak Splitting: 대칭 vs 비대칭 진동
Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these ...
IR 분광법의 응용: 개요
IR 분광법의 응용: 개요
The non-destructive nature and ability to provide valuable chemical information make IR spectroscopy a versatile technique with broad applications in ...
Attenuated Total Reflectance(ATR) 적외선 분광법: 개요
Attenuated Total Reflectance(ATR) 적외선 분광법: 개요
Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely ...
Raman 분광법: 개요
Raman 분광법: 개요
The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of ...
Raman 분광학 기기: 개요
Raman 분광학 기기: 개요
A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector. The monochromatic laser ...
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