Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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12:19 min
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November 29th, 2018
DOI :
November 29th, 2018
•Rozdziały w tym wideo
0:04
Title
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Synthesis of 1,3-Dimesitylimidazolium Tetraphenylborate (IMesH+BPh4‐)
2:49
Photogeneration of 1,3-Dimesitylimidazol-2-ylidene (IMes) and Formation of the 1,3-Dimesitylimidazolium-2-dithiocarboxylate Adduct (IMes-CS2)
4:13
Spectrophotometric Titration of Photogenerated IMes
6:12
Photoinduced Ring-Opening Metathesis Polymerization (PhotoROMP) of Norbornene (NB) in Miniemulsion
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Results: Characterization of N-Heterocyclic Carbene (NHC) Products
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Conclusion
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