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Capítulo 16

Equilíbrio Ácido-Base e Solubilidade

Efeito de Íon Comum
Efeito de Íon Comum
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Tampões
Tampões
A solution containing appreciable amounts of a weak conjugate acid-base pair is called a buffer solution, or a buffer. Buffer solutions resist a change in ...
Equação de Henderson-Hasselbalch
Equação de Henderson-Hasselbalch
The ionization-constant expression for a solution of a weak acid can be written as: Rearranging to solve for [H3O+] yields: Taking the negative ...
Cálculo de Alterações de pH em uma Solução Tampão
Cálculo de Alterações de pH em uma Solução Tampão
A buffer can prevent a sudden drop or increase in the pH of a solution after the addition of a strong acid or base up to its buffering capacity; however, ...
Eficácia dos Tampões
Eficácia dos Tampões
Buffer solutions do not have an unlimited capacity to keep the pH relatively constant . Instead, the ability of a buffer solution to resist changes in pH ...
Cálculos de Titulação: Ácido Forte - Base Forte
Cálculos de Titulação: Ácido Forte - Base Forte
Calculating pH for Titration Solutions: Strong Acid/Strong Base A titration is carried out for 25.00 mL of 0.100 M HCl (strong acid) with 0.100 M of a ...
Cálculos de Titulação: Ácido Fraco - Base Forte
Cálculos de Titulação: Ácido Fraco - Base Forte
Calculating pH for Titration Solutions: Weak Acid/Strong Base For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be ...
Indicadores
Indicadores
Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein ...
Titulação de um Ácido Poliprótico
Titulação de um Ácido Poliprótico
A polyprotic acid contains more than one ionizable hydrogen and undergoes a stepwise ionization process.  If the acid dissociation constants of the ...
Equilíbrio de Solubilidade
Equilíbrio de Solubilidade
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many ...
Fatores que Afetam a Solubilidade
Fatores que Afetam a Solubilidade
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Formação de Íons Complexos
Formação de Íons Complexos
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition ...
Precipitação de Íons
Precipitação de Íons
Predicting Precipitation The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is: It is important to realize ...
Análise Qualitativa
Análise Qualitativa
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a ...
Curvas de Titulação Ácido-Base
Curvas de Titulação Ácido-Base
A titration curve is a plot of some solution property versus the amount of added titrant. For acid-base titrations, solution pH is a useful property to ...
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