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Chapter 16

Acid-base and Solubility Equilibria

Common Ion Effect
Common Ion Effect
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Buffers
Buffers
A solution containing appreciable amounts of a weak conjugate acid-base pair is called a buffer solution, or a buffer. Buffer solutions resist a change in ...
Henderson-Hasselbalch Equation
Henderson-Hasselbalch Equation
The ionization-constant expression for a solution of a weak acid can be written as: Rearranging to solve for [H3O+] yields: Taking the negative ...
Calculating pH Changes in a Buffer Solution
Calculating pH Changes in a Buffer Solution
A buffer can prevent a sudden drop or increase in the pH of a solution after the addition of a strong acid or base up to its buffering capacity; however, ...
Buffer Effectiveness
Buffer Effectiveness
Buffer solutions do not have an unlimited capacity to keep the pH relatively constant . Instead, the ability of a buffer solution to resist changes in pH ...
Titration Calculations: Strong Acid - Strong Base
Titration Calculations: Strong Acid - Strong Base
Calculating pH for Titration Solutions: Strong Acid/Strong Base A titration is carried out for 25.00 mL of 0.100 M HCl (strong acid) with 0.100 M of a ...
Titration Calculations: Weak Acid - Strong Base
Titration Calculations: Weak Acid - Strong Base
Calculating pH for Titration Solutions: Weak Acid/Strong Base For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be ...
Indicators
Indicators
Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein ...
Titration of a Polyprotic Acid
Titration of a Polyprotic Acid
A polyprotic acid contains more than one ionizable hydrogen and undergoes a stepwise ionization process.  If the acid dissociation constants of the ...
Solubility Equilibria
Solubility Equilibria
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many ...
Factors Affecting Solubility
Factors Affecting Solubility
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Formation of Complex Ions
Formation of Complex Ions
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition ...
Precipitation of Ions
Precipitation of Ions
Predicting Precipitation The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is: It is important to realize ...
Qualitative Analysis
Qualitative Analysis
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a ...
Acid-Base Titration Curves
Acid-Base Titration Curves
A titration curve is a plot of some solution property versus the amount of added titrant. For acid-base titrations, solution pH is a useful property to ...
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