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Chapitre 16

Réactions acido-basiques et produit de solubilité

Effet d'ion commun
Effet d'ion commun
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Solutions tampons
Solutions tampons
A solution containing appreciable amounts of a weak conjugate acid-base pair is called a buffer solution, or a buffer. Buffer solutions resist a change in ...
Équation de Henderson-Hasselbalch
Équation de Henderson-Hasselbalch
The ionization-constant expression for a solution of a weak acid can be written as: Rearranging to solve for [H3O+] yields: Taking the negative ...
Calcul des changements de pH dans une solution tampon
Calcul des changements de pH dans une solution tampon
A buffer can prevent a sudden drop or increase in the pH of a solution after the addition of a strong acid or base up to its buffering capacity; however, ...
Efficacité d'un tampon
Efficacité d'un tampon
Buffer solutions do not have an unlimited capacity to keep the pH relatively constant . Instead, the ability of a buffer solution to resist changes in pH ...
Calculs de titrage : acide fort - base forte
Calculs de titrage : acide fort - base forte
Calculating pH for Titration Solutions: Strong Acid/Strong Base A titration is carried out for 25.00 mL of 0.100 M HCl (strong acid) with 0.100 M of a ...
Calculs de titrage : acide faible - base forte
Calculs de titrage : acide faible - base forte
Calculating pH for Titration Solutions: Weak Acid/Strong Base For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be ...
Indicateurs de pH
Indicateurs de pH
Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein ...
Titrage d'un polyacide
Titrage d'un polyacide
A polyprotic acid contains more than one ionizable hydrogen and undergoes a stepwise ionization process.  If the acid dissociation constants of the ...
Équilibre de solubilité
Équilibre de solubilité
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many ...
Facteurs affectant la solubilité
Facteurs affectant la solubilité
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Formation d'ions complexes
Formation d'ions complexes
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition ...
Précipitation d'ions
Précipitation d'ions
Predicting Precipitation The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is: It is important to realize ...
Analyse qualitative inorganique
Analyse qualitative inorganique
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a ...
Courbes de titrage acide-base
Courbes de titrage acide-base
A titration curve is a plot of some solution property versus the amount of added titrant. For acid-base titrations, solution pH is a useful property to ...
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