A Dual-Functional Electroactive Filter Towards Simultaneously Sb(III) Oxidation and Sequestration

Summary

A protocol for the rational design of a dual-functional electroactive filter consisting of carbon nanotubes and titanate nanowires is reported and their environmental applications towards Sb(III) oxidation and sequestration is presented.

Abstract

We have designed a facile method to synthesize a dual-functional electrochemical filter consisting of two 1-D materials: titanate nanowires and carbon nanotubes. The hybrid titanate-CNT filter was prepared by a sonication coupled with a post-filtration route. Due to the synergistic effects of the increased number of exposed sorption sites, electrochemical reactivity, small pore size of the titanate-CNT network coupled with a flow-through design, simultaneous Sb(III) oxidation and sequestration can be readily achieved. Atomic fluorescence spectrometer technology demonstrated that the applied electrical field accelerates the Sb(III) conversion rate and the as-obtained Sb(V) were adsorbed effectively by the titanate nanowires due to their Sb specificity. This protocol provides a practical solution for the removal of highly toxic Sb(III) and other similar heavy metal ions.

Introduction

Recently, the environmental pollution caused by emerging antimony (Sb) has attracted much attention^1,2. Extensive studies demonstrate that Sb compounds pose high toxicity to human and microorganisms, although present in low concentrations in the environment^3,4. Even worse, conventional physicochemical or biological methods are usually ineffective to remove these emerging contaminants due to their low concentrations and high toxicity⁵. The most abundant species of Sb are Sb(V) and Sb(III), of which the latter form is more toxic.

Among the currently available treatment methods, adsorption is believed to be a promising and feasible alternative due to its high efficiency, low cost, and simplicity^6,7. Till now, several nanoscale sorbents with tunable microstructures, large specific surface area and Sb specificity have been developed, such as TiO₂⁸, MnO₂⁹, titanate¹⁰, zerovalent iron¹¹, iron oxides and other binary metal oxides^12,13. A common problem when dealing with nanoscale adsorbents is the post-separation issue due to their small particle size. One strategy to address this issue is to load these nano-sorbents onto macro/micro-scale supports¹⁴. Another challenging issue restricting the wide application of adsorption technology is the poor mass transport caused by limited concentration of target compounds/molecules¹⁵. This issue may be partially addressed by adopting a membrane design and convention could enhance the mass transport significantly. Recent efforts have been devoted to develop advanced treatment systems that combine adsorption and oxidation in a single unit for effective Sb(III) removal. Here, we show how an electroactive titanate-carbon nanotube (titanate-CNT) filter was rationally designed and applied for the simultaneously adsorption and sequestration of toxic Sb(III). By fine-tuning the titanate loading amount, applied voltage, and flow rate, we demonstrate how the Sb(III) oxidation rate and sequestration efficiency can be tailored correspondingly. Although the fabrication and application of the electroactive filter is shown in this protocol, similar designs can also apply to the treatment of other heavy metal ions.

Minor changes in the fabrication process and reagents may cause significant changes in the morphology and performance of the final system. For instance, the hydrothermal time, temperature, and chemical purity have been shown to affect the microstructures of these nanoscale adsorbents. The flow rate of the adsorbate solution also determines the residence time within a flow-through system as well as the removal efficiency of target compounds. With clear identification of these key impacting parameters, a reproducible synthesis protocol can be secured and a stable removal efficiency of Sb(III) can be achieved. This protocol aims to provide detailed experience on the fabrication of dual-functional hybrid filters as well as their applications towards the removal of toxic heavy metal ions in a flow-through manner.

Protocol

CAUTION: Please carefully read relevant safety data sheets (SDS) of all chemicals and wear proper personal protection equipment (PPE) before use. Some of the chemicals are toxic and irritant. Be careful when handling carbon nanotubes, which may have additional hazards if inhaled or contacted by skin.

1. Preparation of the electroactive titanate-CNT filter

1. Preparation of titanate nanowires¹⁶
   1. Dissolve 56 g of potassium hydroxide (KOH) in 100 mL of deionized water under vigorous stirring.
   2. Add 3 g of titanium dioxide (TiO₂) powder into the as-dissolved KOH solution.
   3. Transfer the above solution into a Teflon-lined reactor and keep it at 200 °C for 24 h.
   4. Wash the obtained white precipitate with 0.1 mol/L hydrochloric acid (HCl) and deionized water until a neutral effluent pH is obtained. Dry the product under vacuum at 60 °C overnight.
   5. Transfer the products to a tube furnace and heat it to 600 °C for 2 h with a ramp rate of 1 °C/min.
2. Preparation of titanate-CNT filter¹⁷
   1. Add 20 mg of carbon nanotubes (CNTs) into 40 mL of n-methyl pyrrolidone (NMP). Probe-sonication for 40 min to obtain homogeneous solution.
   2. Separately, add 20 mg of the as made titanate nanowires into 20 mL of NMP. Perform probe-sonication for 20 min.
   3. Mix the titanate dispersion solution with the CNT dispersion solution. Filter the mixture solution onto a PTFE membrane, which serves as a support for the titanate-CNT filter.
   4. Rinse sequentially with 100 mL of ethanol and 200 mL of deionized water.
      NOTE: A CNT-alone filter can be prepared by a similar route without the addition of titanate nanowires.

2. Electrochemical filtration of Sb(III)

1. Description on the experimental apparatus¹⁸
   1. Conduct the sorption experiments in an electrochemistry modified polycarbonate filtration casing (see Figure 1).
   2. Use a DC power supply to drive the electrochemistry.
   3. Adopt perforated titanium ring as connector for anodic or cathodic filters.
   4. Use an insulating silicone rubber as a separator and seal.
2. Filtration experiments
   1. Add 2.2 mg of C₈H₄K₂O₁₂Sb₂.3H₂O into 1000 mL of deionized water to prepare 800 μg/L Sb(III) solution.
   2. Transfer 100 mL of Sb(III) solution to a 150 mL beaker. Adjust solution pH to 7.
   3. Place the as-prepared titanate-CNT filter anode into the polycarbonate filtration casing and place another CNT-alone filter as cathode. Seal the casing.
   4. Pass through the filtration system with Sb(III) solution at a given flow. Apply a DC voltage during filtration.
   5. Determine the Sb_total and Sb(III) concentration with atomic fluorescence spectrometer technique¹⁷.
      NOTE: In this process, flow rate and applied voltage can be tuned by a peristaltic pump and a DC power supply, respectively.

Results

The electroactive filtration apparatus employed is an electrochemically modified polycarbonate filtration casing (Figure 1). Field emission scanning electron microscope (FESEM) and transmission electron microscopy (TEM) techniques are employed to characterize the morphology of the titanate-CNT filter (Figure 2). To demonstrate the efficacy of the electrochemical filtration system, the change of Sb_total and Sb valence state as a function of time is det...

Discussion

The key to this technology is to fabricate an electroactive conductive and porous hybrid filter with high Sb-specificity. To do this, special care should be paid to the fabrication process. The amount of titanate nanowires need to be precisely controlled due to the "trade-off" effect between the filter's electrical conductivity and surface area.

In addition, it should be also noted that a proper applied voltage is necessary. Once the applied voltage is too high (e.g., >3 V), other competit...

Materials

Name	Company	Catalog Number	Comments
Atomic fluorescence spectrometer	Ruili Co., Ltd
Carbon nanotubes (CNT)	TimesNano Co., Ltd
DC power supply	Dahua Co., Ltd
Ethanol, 96%	Sinopharm
Hydrochloric acid, 36%	Sinopharm		Corrosive
L-antimony potassium tartrate	Sigma-Aldrich		Highly toxic
N-methyl-2-pyrrolidinone (NMP), 99.5%	Sinopharm		Highly toxic
Potassium hydroxide, 85%	Sinopharm		Corrosive
Peristaltic pump	Ismatec Co., Ltd
Titanium dioxide powders	Sinopharm