JoVE Logo
Faculty Resource Center

Sign In

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

DOI :

10.3791/50886-v

September 8th, 2013

September 8th, 2013

10,712 Views

1Department of Chemistry and Biochemistry, University of North Carolina at Greensboro

Herein is described the synthesis, isolation, and reactions of hypervalent iodonium alkynyl triflates (HIATs) with azides to generate cyanocarbenes. The procedures will involve air-sensitive and cryogen techniques, including cold filtration under an inert atmosphere. Handling and safety of the synthesized compounds will also be discussed.

Tags

Keywords Hypervalent Iodonium Alkynyl Triflates

-- Views

Related Videos

article

Synthesis, Cellular Delivery and In vivo Application of Dendrimer-based pH Sensors

article

Split-and-pool Synthesis and Characterization of Peptide Tertiary Amide Library

article

Synthesis of Indoxyl-glycosides for Detection of Glycosidase Activities

article

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives

article

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin

article

Synthesis of Protein Bioconjugates via Cysteine-maleimide Chemistry

article

Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst

article

Synthesis and Mass Spectrometry Analysis of Oligo-peptoids

article

Enzymatic Cascade Reactions for the Synthesis of Chiral Amino Alcohols from L-lysine

article

Synthesis of Substrate-Bound Au Nanowires Via an Active Surface Growth Mechanism

JoVE Logo

Privacy

Terms of Use

Policies

Research

Education

ABOUT JoVE

Copyright © 2024 MyJoVE Corporation. All rights reserved